POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST

• 来源期刊: 高分子科学（英文版）
• 学科: 化学
• 年，卷（期）: 1998,（2）
• 页码范围: 126-132
• 页数: 7页
• 分类号: O6
• 语种: 英文

摘要

The polymerization mechanism is described by the conductance change with the time during the polymerization. The mechanism can be explained by the equilibrium feature (i.e. main ion-pairs) between the free ions and the ion-pairs dissociated by the organic salt (-) Sp*+ (+) CSA*- (An asterisk represents the chirality) and the scheme of the polymerization process isdescribed mainly by the charge transfer complexes having chiral induction power.