A trinuclear linear Mo-Fe-Mo dialkyldithiocarbamate complex [Et4N] {[Me2dtcMoO(μ-S)2]2Fe} has been obtained and structurally characterized, which contains two Me2dtcMoO(μ-S)2 units coordinated to a central tetrahedral Fe atom. A comparison of the structural parameters indicates the metal oxidation states of 2Mo(v) + Fe(Ⅲ). The 1H NMR shows chemical shifts of Me2dtc ligands at δ 10.14 and δ 9.40 with the intensity ratio of 1:1. The cyclic voltammogram displays a reversiible couple at - 1.41 V/- 1.36 V responsible for 1-/2-anions of the complex and an irreversible oxidation at 0.5 V,which seems to show the apparent lack of stability for its neutral species (Me2dtcMoOS2)2Fe.