Synthesis, characterization and application of soluble fullerenat ed polymer materials

• 来源期刊: 中国化学(英文版)
• 年，卷（期）: 2000,（5）
• 页码范围: 651-664
• 页数: 14页
• 语种: 英文

摘要

This article only deals with the topic of intense interest to us and to a considerable extent of our own experimental results on the synthesis, characterization and application of C60-con taining functional polymers such as poly (N-vinylcarbazole), polyrene and polyacrylonitrne-based fullerene polymers. The results demonstrate that [60] fullerene can be directly in corporated into a variety of functional polymers by copolymer ization or grafting, but also can be used to modify or improve the electronic, optiical and physicochemical properties of poly mers. Both the stereo-electroniceffect and the steric hindrance of C60 have an important influence on the structu-e and physicochemical properties of the parent polymer.