Bis-perfluoroalkylation of aromatic compounds with sodium perfluoroalkanesulfinates

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2000,（3）
• 页码范围: 402-406
• 页数: 5页
• 语种: 英文

摘要

Bis-perfluoroalkylation of aromatic compounds such as dimethoxybenzenes (2,4,6), anisole (8), pyridine (10) and quinoline (13) was accomplished by reaction with excess sodium perfluoroalkanesulfinates, RFSO2Na (1), in the presence of Mn(OAc)3·2H2O under mild conditions. The reaction provides a facile method for the synthesis of bis-perfluoroalkylated aromatic compounds.