A new strategy for the synthesis of unsymmetrical phosphotriesters

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2000,（2）
• 所属期刊栏目: Articles
• 页码范围: 232-235
• 页数: 4页
• 分类号: O6
• 语种: 英文

摘要

A new strategy for the synthesis of unsymmetrical phosphotriesters was reported: an alcohol was converted to umsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmitricai triesters in the presence of iodine in high yields under exceptionally mild conditions.