Inclusion property and Diels-Alder reaction of bis (diphenyl-phosphine oxide) butadiyne
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摘要:
The host molecule, bis( diphenylphosphine oxide ) butadiyne (2), includes a variety of guests to form five complexes (2a-2e). In addition, the Diels-Alder reaction between 2 and anthracene gives 9, 9', 10, 10'-tetrahedron-9, 9', 10, 10'-bi-ethenoantracene- 11, 11'-bis ( diphenylphosphine oxide ) ( 3 )which is a potential di-π-methane reactant and can undergo photorearrangement.