Photoinduced charge injection from excited triplet hypocrellin B
into TiO2 colloid in ethanol
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摘要:
Photosensitization of TiO2 colloid by hypocrellin B (HB), a
natural photodynamic pigment with extremely high plhotosta
bility, has been studied by surface enhanced Raman spec
troscorpy (SERS), laser flash photolysis and electron param
agnetic resonance (EPR) techniques. The photosensitization
of TiO2 occurred practically from the excited triplet dye and
the electron injection rate constant is 1.3 × 106 s-1. The influ
ences of donor and acceptor on the eleciron injection were in
vestigated.