Application of Sm0/Auxiliary and Sm0/MCln System in Organic Synthesis

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（2）
• 页码范围: 123-130
• 页数: 8页
• 分类号: O6
• 语种: 英文

摘要

Though samarium metal itself has strong reducingpower, in most cases, certain additives are still needed when it is used as a reductant because the surface of samarium metal is inactive.Thus Sm0/auxiliary systems are proposed.The explored systems include: Sm0/I2,Sm0/TMSCl, Sm0/THF-NH4Cl (aq.), Sm0/Cp2TiCl2,Sm(Hg), Sm0/cat.KI etc.