Molecular and Crystal Magnetic Engineering of Polymetallic Coupling System: From Magnetic Molecules to Molecular Magnets

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（3）
• 页码范围: 208-221
• 页数: 14页
• 分类号: O6
• 语种: 英文

摘要

One of the main challenges in the field of molecular materials is the design of molecular ferromagnets. General design strategy includes two steps, that is molecular magnetic engineering and crystal magnetic engineering. The first step is the synthesis of ferromagnetically coupled polymetallic systems.Tne second step is the assembly of polymetallic systems with muti-dimensional structure and exhibiting a ferromagnetic transition.This paper summarized the strategies of molecular design and crystal engineering allowed to obtain such systems and our efforts in the fields of molecular magnetism and molecular-based magnets.