Solid-state Asymmetric Reduction of (S)-1, l'-Bi-2-naphtholAcetylferrocene Molecular Compound with Sodium Borohydride

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（7）
• 所属期刊栏目: Communications
• 页码范围: 716-718
• 页数: 3页
• 分类号: O6
• 语种: 英文

摘要

A novel molecular crystal formed between enanteopure 1,l'bi-2-naphthoi and acetylferrocene has been prepared andcharacterized in this communication. The examination on itsreducton with soditma borohydride showed that the asymnetric inducton was observed in the solid state but not in the solution phase. The asymmetric induction in the solid-state reaction may be attributed to the chiral microenviromnent ofmolecular crystal.