Crystal Structure and Characterization of Pd(Ⅱ) Bis(diisopropyldithiocarbamate) Complex

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（4）
• 所属期刊栏目: NOTE
• 页码范围: 436-440
• 页数: 5页
• 分类号: O6
• 语种: 英文

摘要

The crystal and molecular structure of [Pd(iPr2 dtc)2] (dtc=dithiocarbamate) have been determined by X-ray crystallography. The unit cell of the crystal structure consists of two discrete monomeric molecules of [Pd(iPr2dtc)2]. The Pd(Ⅱ)ion has an square-planar. The electronic and IR spectral data are in agreement with the X-ray structure. The TG data indicate slight degradation of a few percent.