Allylation of Diselenides, Aldehydes and Ketones with Ytterbium/Allyl Bromide System

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（4）
• 所属期刊栏目: ARTICLES
• 页码范围: 381-385
• 页数: 5页
• 分类号: O6
• 语种: 英文

摘要

In the presence of methyliodide, ytterbium can react with allyl bromide smoothly to form allylytterbium bromide, which fur ther reacts with diselenides, aldehydes and ketones to afford allylselenides and homoallylic alcohols respectively in good yields under mild and neutral conditions.