Synthesis,Characterization and CD Spectra Studies of Chiral Calixsalen Complexes

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（12）
• 页码范围: 1296-1301
• 页数: 6页
• 分类号: O6
• 语种: 英文

摘要

A chirai macrocyclic Schiff base ligand and its binuclear metalcomplexes of Fe,Co,Ni and Cu were synthesized by a madifled method with 1,2-diaminocydohexane as the starting material,which is readily obtained.The characters of those com-plexes were studied by elenental analyses,MS,NMR,FT-IR.UV-Vis and CD ( Circular Dichroism) spectra.Further-more,the electronic absorption spectra and CD spectra prop-erties of the chiral complexes were discussed.``