Reactions of Fluoroalkanesulfonyl Azides with Diethyl Phosphite,A New Method for the Synthesis of N-Fluoroalkanesulfonylphosphoramidates

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（12）
• 页码范围: 1259-1262
• 页数: 4页
• 分类号: O6
• 语种: 英文

摘要

N-Fluoroalkanesulfonylphosphorates,RfSO2NHP(O)(OEt)2,have been prepared by a one-step reaction of fluoroalkanesulfonyl azides (RfSO2N3) with diethyl phosphite at room temperature.The reaction mechanism was also discussed and a favored mechanisn was suggested.``