Synthesis and Disproportionation of Mixed Ligand IndiumOrganometallics Involving Ethyl and β-Diketonate Chelate Ligands

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2001,（1）
• 页码范围: 109-112
• 页数: 4页
• 分类号: O6
• 语种: 英文

摘要

Twelve compounds either of type Et2In(diket) or EtIn(diket)2 (diket=β-diketonate) have been synthesized, and all these compounds tend to disproportionate into Et3In and In(diket)3 at moderately high temperature. Compounds of the latter type are much more thermally stable than those of the former. Moreover, In(CH3COCHCOCH3)3 has been synthesized and its crystal structure has been determined.