Cupric Hexacyanoferrate Nanoparticle Modified Carbon Ceramic Composite Electrodes

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2002,（4）
• 页码范围: 374-380
• 页数: 7页
• 语种: 英文

摘要

Graphite powder-supported cupric hexacyanoferrate (CuHCF)nanoparticles were dispersed into methyltrimethoxysilane-based gels to produce a conducting carbon ceramic composite, which was used as electrode material to fabricate surface-renewable CuHCF-modified electrodes. Electrochemical behavior of the CuHCF-modified carbon ceramic composite electrodes was characterized using cyclic and square-wave voitammetry.Cyclic voltammograms at various scan rates indicated that peak currents were surface-confined at low scan rates. In the presence of glutathione, a clear electrocatalytic response was observed at the CuHCF-modified composite electrodes. In addition, the electrodes exhibited a distinct advantage of reproducible surface-renewal by simple mechanical polishing on emery paper, as well as ease of preparation, and good chemical and mechanical stability in a flowing stream.