Synthesis, Characterization and Crystal Structure of Chlorodibenzyltin(Ⅳ) Complex with Dithiomorpholinocarbamate Ligand

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2002,（9）
• 页码范围: 913-916
• 页数: 4页
• 语种: 英文

摘要

Chlorodibenzyltion(Ⅳ) complex with dithiomorpholinocarbamate ligand was synthesized by the reaction of dibenzyltin dichloride with dithiomorpholinocarbamate in 1:1 stoichiometry. The complex was characterized by elementary analysis, UV, IR and 1H NMR spectra. The crystal structure was determined by X-ray single crystal diffraction study. The crystallographic data are as follows; triclinic, space group P1, a=0.8723(2)nm, b=1.099(2) nm,c=1.1036(3) nm, α=86.498(4)。,β=89.697(5)。,γ=82.807(5)。,Z=2,V=1.0479(4) nm3, Dc=1.580 g/cm-3,μ=1.553 mn-1,F(000)=500,R1=0.0442,wR2=0.0974. The crystal consists of discrete molecules containing five-coordinate in atoms in a distorted tigonal bipyramidal configuration. The molecules are packed in the unit cell in one-dimensional chain structure through a weak interaction between the chlorine atom and sulfure satom, the sulfur atom and one of the sulfurs of an adjacent molecule.