Optical Constants of Palladium Phthalocyanine Derivative Thin Films
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摘要:
Ellipsometric parameters ora series of spin-coated thin films of palladium phthalocyanine derivatives with bromine and tetraalkoxyl substitutes (PdPc(OC8H17)4Brm, m = 0, 2, 3, 4) are determined from a rotating analyserpolarizer type of scanning ellipsometer. The optical, dielectric constants and absorption coefficients of the films in the 500-800nm wavelength region are reported. The results show that refractive index N (N = n- k),dielectric constant ε (ε =ε1 -ε2) and absorption coefficient α in the region 500-800nm are influenced by bromine atom substituted on the conjugated phthalocyanine ring regularly. It is found that there is approximately a linear relationship between the resonance absorption wavelengths of the films and the number of bromine atoms substituted on the phthalocyanine ring.