[Co(H2O)(HPO4)]·H2O: The Layered Divalent Metal Monohydrogenphosphate Structure

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2002,（1）
• 页码范围: 34-38
• 页数: 5页
• 语种: 英文

摘要

A new layered divalent metal monohydrogenphosphate [ Co(H2O) (HPO4)] @H2O (1) was hydrothermally synthesized from the reaction of CoCl2 @6H2O with H3PO4 in the presence of cis-Pt(NH3)2Cl2 and ethylenediamine. The structure features extensive intra- and inter-layer hydrongen bonding among the hydrogenphosphate anoin, the coordinated water and the crystallization water. X-ray crystallographic parameters for 1 are orthorhombic Pnma ( # 62), a = 1.7528 (2),b=0.56158(7), c=0.47867(6) nm, V=0.47116(9) nm3,Z=4