Determination of the Geometric Structure of Core Excited Silane Based on Photoabsorption Spectra Near the Si 2p Edges

• 来源期刊: 中国物理快报（英文版）
• 学科: 物理学
• 年，卷（期）: 2002,（8）
• 页码范围: 1085-1087
• 页数: 3页
• 分类号: O4
• 语种: 英文

摘要

The photoabsorption spectra near the Si 2p edges of SiH4 have been studied based on the multiple-scattering selfconsistent-field method. Our theoretical calculations provide clear assignments of the inner-shell photoabsorption spectra. In comparison with high-resolution experimental spectra, the geometric structure of the Si 2p excited SiH14** is recommended as C2v symmetry.