Homocoupling of Aryl Iodides Catalyzed by Cyclopalladated Complexes of Tertiary Arylamines
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摘要:
Homocoupling of aryl iodides catalyzed by cyclopalladated complexes of tertiary arylamines gives symmetric biaryls with good yields in DMA or ionic liquid [Bmim]BF4.This catalytic alternative of the Ullmann reaction has proved to be sensitive to both electronic and steric factors of substrates.