Thermal Behavior of N,N'-Bis[N-(2,2,2-trinitroethyl)-N-nitro]ethylenediamine

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2004,（7）
• 页码范围: 658-660
• 页数: 3页
• 语种: 英文

摘要

The thermal behavior and kinetic parameters of the exothermic decomposition reaction of N,N'-bis[N-(2,2,2-trinitroethyl)-N-nitro]ethylenediamine in a temperature-programmed mode have been investigated by means of differential scanning calorimetry (DSC). The results show that kinetic model function in differential form, apparent activation energy Ea and pre-exponential factor A of this reaction are 3(1-α)2/3, 203.67 kJ·mol-1 and 1020.61 s-1, respectively. The critical temperature of thermal explosion of the compound is 182.2 ℃. The values of △S≠, △H≠ and △G≠ of this reaction are 143.3 J·mol-1·K-1, 199.5 kJ·mol-1 and 135.5 kJ·mol-1, respectively.