Effects of Temperature Raising Speed on the Growth of BN Crystals in Hydrothermal Solutions

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2004,（6）
• 页码范围: 528-532
• 页数: 5页
• 语种: 英文

摘要

Cubic boron nitride (cBN) and orthorhombic boron nitride (oBN) crystals have been prepared in hydrothermal solutions by reacting H3BO3+NaN3+P and H3BO3+NaN3+N2H4 respectively. The experimental results indicated that, if the temperature was increased rapidly, both the yield and perfectness of BN crystals became poor. On the contrast, the yield and perfectness of BN crystals can be improved very much by slowly increasing the temperature of the reaction mixture. The results of X-ray powder diffraction (XRD), Fourier transform infrared spectrum (FTIR)and high resolution transmission electron microscopy (HRTEM) proved that the samples were composed of oBN and cBN.