A Three-dimensional Heteronuclear Polymer of [Ag2Fe(SCN)5- (DMF)]n Containing Channels and One-dimensional Ag2S2-S-Ag2S2 Chains with Ag…Ag Interaction

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2004,（6）
• 页码范围: 533-536
• 页数: 4页
• 语种: 英文

摘要

The Ag2S2 rings connect [Fe(NCS)5(DMF)]2 (DMF=N,N-dimethylformamide) octahedrons by bridging thiocyanates leading to a 3-D [Ag2Fe(SCN)5(DMF)]n framework. The Fe(III) atoms are in the octahedral geometry and Ag(I) atoms are in the distorted tetrahedral geometry. One-dimensional Ag2S2-S-Ag2S2 wave-like strand chains along the b-axis and channels constructed from ten-membered Ag2Fe(SCN)2S rings along the c-axis feature the three-dimensional framework. The Ag…Ag distance of 0.3103(1) nm in Ag2S2 rings indicates weak Ag…Ag interaction. Such an Ag2S2-S-Ag2S2 chain in silver(I) complexes is unprecedented. Crystal data:Mr=635.09, orthorhombic, Pnma, a= 1.64214(13) nm, b= 1.40075(11) nm, c=0.84445(7) nm, V=1.9424(3) nm3, Z=4,μ(Mo Kα)=3.278 mm-1, Dcalcd=2.172 g· cm-3, F(000)=1220, R1 =0.0443, wR2=0.1138.