Dramatic Substituent Effect on the CCL-catalyzed Kinetic Resolution of 1-Aryl-2,3-allenols

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2004,（3）
• 页码范围: 310-314
• 页数: 5页
• 分类号: O6
• 语种: 英文

摘要

Optically active 1-aryl-2,3-allenols were obtained via CCL-mediated kinetic resolution of the racemic allenols. The substitution pattern of the aromatic ring, regarding to both the type of the substituent and its position on the aromatic ring, was found to be critical for the kinetic resolution of 1-aryl-2,3-allenols.