Some Attempts to Employ the Singlet Oxygen Generated from H2O2
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摘要:
Some attempts to employ the singlet oxygen generated from molybdate-catalyzed decomposition of hydrogen peroxide are presented. Reduction of ascaridole with diimide is also described, along with the preliminary results of the cleavage study using Fe-cysteinate as a simple model for F.e-S type redox species. There were strong indications that S-alkylation occurred as observed in similar cleavage of the potent antimalarial qinghaosu.