Cation Guided Assembly: Crystal Structures of Two Ag(I) Complexes in Versatile Dimensionalities with Different Counter Cations

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2006,（4）
• 页码范围: 493-498
• 页数: 6页
• 语种: 英文

摘要

Assembly of [Ag(CN)2]- units with M(Ⅱ)-diamine complex cations [Cu(LN-N)2]2+, where LN-N represents1,2-diaminopropane (pn) and ethylenediamine (en), afforded two complexes, [Cu(pn)2][Ag2(CN)4] (1) and[Cu(en)2][Ag3(CN)5] (2), which were characterized by elemental analysis, IR, UV-Vis and ESR spectra. Single crystal X-ray analyses show that these complexes have 2D and 3D architectures through silver-silver interactions and other weak interactions. The luminescence behaviors of the two complexes were also studied by means of emission spectra.