Synthesis and Characterization of a Noncovalently Linked Porphyrin-[1,2-(1-acridin-10'-yl-2-aza-2-methylprop-1,3-ylene)-fullerene] Dyad

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2006,（7）
• 页码范围: 862-866
• 页数: 5页
• 语种: 英文

摘要

1,2-(1-Acridin-10'-yl-2-aza-2-methylprop-1,3-ylene)fullerene was synthesized firstly and characterized by UV-Vis, 1H NMR, 13C NMR and electrospray ionization mass spectroscopy, which is capable of forming a stable complex with zinc tetraphenylporphyrin via the axial ligation. The steady state fluorescence studies show efficient quenching of the zinc tetraphenylporphyrin emission upon axial coordination of acridine attached to C60.