Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium(Ⅲ)-PYBOX Complex

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2006,（10）
• 页码范围: 1439-1442
• 页数: 4页
• 语种: 英文

摘要

An indium complex of chiral pyridine bis(oxazoline) (PYBOX) has been applied to the catalytic asymmetric allylation of ketones. It has been found that this chiral indium complex is strong enough to promote the reaction of ketones with allyltributylstannane smoothly. The products were obtained in moderate yields with low to moderate enantioselectivities.