Non-Isothermal Decomposion Kinetics of Supermolecule Compound [Eu(C10H9N2O4)(C10H8N2O4)(H2O)3]2·phen·4H2O

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2006,（12）
• 页码范围: 1731-1736
• 页数: 6页
• 语种: 英文

摘要

Europium(Ⅲ) compound with 2-oxopropionic acid salicyloyl hydrazone (C10H10N2O4, H3L) and 1,10-phenanthroline (C12HsN2, phen) has been prepared. A yellow prismatic crystal of the compound was obtained, and the molecule crystallized in the triclinic space group P-1. There are two 9-coordinated complex molecules in every structure unit, where every Eu atom is coordinated by three water molecules and two tridentate C10H10N2O4 ligands,forming two stable pentacycles. The coordination polyhedron around Eu3+ was described as a single cap square antiprism. In the crystal cell, there are one free 1,10-phenanthroline and four water molecules. The thermal decomposition of the compound and its kinetics were studied by non-isothermal thermogravimetry. The Kissinger's method and Ozawa's method were used to calculate the activation energy value of the first-step decomposition. The stages of the decompositions were identified by TG-DTG-DSC curve. The non-isothermal kinetic data were analyzed by means of integral and differential methods. The possible reaction mechanism and the kinetic equations were investigated by comparing the kinetic parameters.