The role of hydrogen in hydrogenated microcrystalline silicon film and in deposition process with VHF-PECVD technique

• 来源期刊: 中国物理（英文版）
• 关键词: VHF-PECVD technique hydrogenated microcrystalline silicon role of hydrogen optical emission spectroscopy
• 年，卷（期）: 2006,（6）
• 页码范围: 1374-1378
• 页数: 5页
• 语种: 英文

摘要

The role of hydrogen in hydrogenated microcrystalline silicon (μc-Si:H) thin films in deposition processes with very high frequency plasma-enhanced chemical vapour deposition (VHF-PECVD) technique have been investigated in this paper. With in situ optical emission spectroscopy (OES) diagnosis during the fabrication ofμc-Si:H thin films under different plasma excitation frequency ve (60MHz-90MHz), the characteristic peak intensities (ISiH*, IHα* and IHβ* ) in SiH4+H2 plasma and the ratio of (IHα* + IHβ* ) to ISiH* were measured; all the characteristic peak intensities and the ratio (IHα* + IHβ* )/ISiH* are increased with plasma excitation frequency. It is identified that high plasma excitation frequency is favourable to promote the decomposition of SiH4+H2 to produce atomic hydrogen and SiHx radicals. The influences of atomic hydrogen on structural properties and that of SiHx radicals on deposition rate of μc-Si:H thin films have been studied through Raman spectra and thickness measurements, respectively. It can be concluded that both the crystalline volume fraction and deposition rate are enhanced with the increase of plasma excitation frequency, which is in good accord with the OES results. By means of FTIR measurements, hydrogen contents ofμc-Si:H thin films deposited at different plasma excitation frequency have been evaluated from the integrated intensity of wagging mode near 640 cm-1. The hydrogen contents vary from 4% to 5%, which are much lower than those of μc-Si:H films deposited with RF-PECVD technique. This implies that μc-Si:H thin films deposited with VHF-PECVD technique usually have good stability under light-soaking.