Rapid Thermolysis Studies of [Pb2(TNR)2(CHZ)2(H2O)2]·4H2O and Cd(CHZ)2(TNR)(H2O)

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2007,（7）
• 页码范围: 906-909
• 页数: 4页
• 语种: 英文

摘要

T-jump/FT-IR spectroscopy was used to study the rapid thermal decomposition activity of the major gaseous products of flash pyrolysis of Cd(CHZ)2(TNR)(H2O). Thus Cd(CHZ)2(TNR)(H2O) is not an eco-friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of tion products and the amount of NO is less than the experiment result from T-jump/FTIR.