The First Homochiral Diamond-Like Coordination Polymer Containing Cubane Cluster (Cu4l4) as Connecting Node and Cinchonine as Donor-Acceptor (or Push-Pull Electronic Effect) Building Block

• 来源期刊: 中国化学(英文版)
• 年，卷（期）: 2007,（10）
• 页码范围: 1405-1408
• 页数: 4页
• 语种: 英文

摘要

The reaction of CuI with cinchonine (an organic donor-acceptor chromophore) afforded a homochiral 3D diamondoid network [Cu4I4(cinchonine)2]n (1) containing a cubane cluster (Cu4I4) as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a cluster as a connecting note. Its thermal stability and solid state optical properties such as fluorescence, circular dichroism and second-harmonic generation response were also reported.