Nitrogen-rich 6-(3,5-Dimethylpyrazol-1-yl)-3-(2,4,6-trinitroanilino)-1,2,4,5-tetrazin: Synthesis, Crystal Structure and Thermal Property

• 来源期刊: 中国化学(英文版)
• 年，卷（期）: 2007,（10）
• 页码范围: 1451-1454
• 页数: 4页
• 语种: 英文

摘要

6-(3,5-Dimethylpyrazol-1-yl)-3-(2,4,6-trinitroanilino)-1,2,4,5-tetrazin (1) has been synthesized and characterized by 1H NMR, MS, elemental analysis, infrared spectra and thermal analyses. The crystal structure was determined by X-ray diffraction method. 1 is crystallized in P21/c space group of monoclinic crystal system, and exhibits good physical properties, such as high densities (＞ 1.55 g·cm-3) and good thermal stabilities (Td＞220 ℃). The intrermolecular hydrogen bonds construct the P- and M-helices from organic molecules and may contribute to the high melting points.