Study on Cyclometalated Palladium-azo Complexes as Colorimetric Probes for Hazardous Gas in Water

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2007,（6）
• 页码范围: 797-801
• 页数: 5页
• 语种: 英文

摘要

A synthesized cyclometalated palladium-azo complex was explored as a multifunctional probe for visual detection of SO2, H2S and NH3 in water. In acidic aqueous environment, the sensing solution underwent a sharp color change from poor violet to deep blue when titrated with Na2SO3 standard solution. But the color changed from poor violet to bright yellow when titrated with Na2S standard solution. In basic environment, the sensing solution rapidly changed to magenta when titrated by NH4Cl-NH3 standard buffer solution at high concentration. However, the color of sensing solution changed to blue when titrated by NH4Cl-NH3 standard buffer solution at low concentration although the pH was kept constant during the titration. Different species of these hazardous gases at environmentally relevant concentration levels were differentiated by independent optical signal outputs, and the interference from other inorganic ions commonly existing in water was very small.