Total Synthesis of 4"-O-Acetylmananthoside B Part Ⅱ: Synthesis of the Disaccharide Fragment
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摘要:
A disaccharide compound, p-methoxyphenyl 2,3,4-tri-O-benzyl-β-L-arabinopyranosyl-(1→6)-2-O-benzyl-3,4-di-O-acetyl-β-D-galactopyranoside (17), was successfully synthesized from two monosaccharides L-arabinose and D-galactose and fully characterized. This compound can be used to build a natural product 4"-O-acetylmanan thoside B, which was isolated from the leaves and stems of a kind of Vietnamese Acanthaceae Justicia patentiflora.