Synthesis of Enantiopure SunPhos Diphosphine and Its Reaction with Methyl Acrylate

• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2008,（11）
• 页码范围: 2098-2102
• 页数: 5页
• 语种: 英文

摘要

A procedure of synthesizing enantiopure SunPhos diphosphine from its corresponding diphosphate was reported.The SunPhos diphosphine can be employed as a useful intermediate to make a variety of electron-rich biaryl phosphine ligands by reacting the-PH2 group with C=C,C=O double bonds or other electrophiles.