Crystal structure and photoelectricity property of Fe(Ⅱ/Ⅲ) coordination supermolecules

• 来源期刊: 科学通报(英文版)
• 学科: 化学
• 关键词: 表面光电压 晶体结构 铁离子 超分子 一维链状结构 近红外光谱 单晶X射线衍射 phen
• 年，卷（期）: 2010,（2）
• 所属期刊栏目: ARTICLES
• 页码范围: 124-130
• 页数: 7页
• 分类号: O614.121 TN304.12
• 语种: 英文

摘要

Three new mixed-ligand Fe(Ⅱ/Ⅲ) complexes [Fe2(μ2?btec)( μ2?H2btec)(phen)2(H2O)2]n (1), [Fe2(btec) (phen)2(H2O)4] (2), and {[Fe(o-pha)(phen)(H2O)]?H2O}n (3) (phen=1,10-phenanthroline, o-H2pha=o-phthalic acid, H4btec=1,2,4,5-benzenetetracarboxylic acid) have been hydrothermally synthesized and detected by single crystal X-ray diffraction, showing that complexes (1) and (2) are both bridged by the betc4? ligands to form 1D chain and dinuclear structure and complex (3) is bridged by the o-pha groups to form 1D ...