An empirical technique to evaluate the UV irradiation time for highly polluted waters prior to ASV detection

• 来源期刊: 科学通报(英文版)
• 学科: 化学
• 关键词: 紫外线照射 照射时间 ASV 技术评估 重污染 阳极溶出伏安法 金属配合物 检测
• 年，卷（期）: 2010,（2）
• 所属期刊栏目: ARTICLES
• 页码范围: 140-144
• 页数: 5页
• 分类号: O641.4 TS103.823
• 语种: 英文

摘要

Conducting anodic stripping voltammetry (ASV) to determine non-labile-form metal in a water sample usually requires UV digestion. The time for thoroughly disintegrating metal complexes is lengthy and completion of digestion is not easy to determine. In this study, the degree of dissociation of copper complex, indicated by the ratio of slope changes at ASV titration, was found to be linearly correlated with UV irradiation time (r 2 = 0.976). Using slope changes, an equation for estimating the length of UV ir...