Fabrication of Nanocrystalline TiO<sub>2</sub>Thin Film Ammonia Vapor Sensor

• 作者: Bharat Raut Dhanaji Dalvi Manik Chougule Pradeep Joshi Pramod Patil Sanjay Patil Shailesh Pawar Shashwati Sen Vikas Patil
• 来源期刊: 传感技术(英文)
• 学科: 化学
• 关键词: SOL Gel Method Structural PROPERTIES Optical PROPERTIES NH3 Sensor
• 年，卷（期）: 2011,（1）
• 页码范围: 9-16
• 页数: 8页
• 分类号: O6

摘要

Nanocrystalline titanium oxide thin films have been deposited by spin coating technique and then have been analyzed to test their application in NH3 gas-sensing technology. In particular, spectrophotometric and con-ductivity measurements have been performed in order to determine the optical and electrical properties of titanium oxide thin films. The structure and the morphology of such material have been investigated by X ray diffraction, Scanning microscopy, high resolution electron microscopy and selected area electron diffrac-tion. The X-ray diffraction measurements confirmed that the films grown by this technique have good crys-talline tetragonal mixed anatase and rutile phase structure The HRTEM image of TiO2 thin film showed grains of about 50-60 nm in size with aggregation of 10-15 nm crystallites. Selected area electron diffraction pattern shows that the TiO2 films exhibited tetragonal structure. The surface morphology (SEM) of the TiO2 film showed that the nanoparticles are fine The optical band gap of TiO2 film is 3.26 eV. Gas sensing proper-ties showed that TiO2 films were sensitive as well as fast in responding to NH3. A high sensitivity for ammo-nia indicates that the TiO2 films are selective for this gas.