Analytical potential energy function and spectroscopyparameters for B1Ⅱ state of KH

• 来源期刊: 中国光学快报（英文版）
• 年，卷（期）: 2011,（12）
• 页码范围: 39-42
• 页数: 4页
• 语种: 英文
• DOI: 10.3788/COL201109.120201

摘要

Multi-reference configuration interaction is used to produce potential energy curves (PECs) for the excited B1Ⅱ state of KH molecule.To investigate the correlation effect of core-valence electrons,five schemes are employed which include the different correlated electrons and different active spaces.The PECs are fitted into analytical potential energy functions (APEFs).The spectroscopic parameters,ro-vibrational levels,and transition frequencies are determined based on the APEFs and compared with available experimental and theoretical data.The molecular properties for B1Ⅱ obtained in this letter,which are better than those available in literature,can be reproduced with calculations using the suitable correlated electrons and active space of orbitals.