Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au (111) surface
Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au (111) surface
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摘要:
The molecular orientation of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) multilayers adsorbed on Au (111) surface has been investigated using angular dependent O K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. The significant angular dependence of important resonant structures (π* and σ*) reveals that PTCDA molecules adopt an ordered geometry on the substrate surface. The average tilt angle of the PTCDA molecular planes is 27°±10° from the Au (111) surface.