A New 1D Zinc Coordination Polymer Constructed by 1-Naphthylacetate and 4,4＇-bpy：Synthesis,Structure and Luminescent Property

• 作者: NIU Xian-Chun ZHOU Jian-Min
• 来源期刊: 结构化学
• 学科: 化学
• 关键词: 锌配位聚合物 一维链状结构 发光性能 联吡啶 萘乙酸 合成 单晶X-射线衍射 构造
• 年，卷（期）: 2012,（3）
• 页码范围: 361-366
• 页数: 6页
• 分类号: O614.241|O614.122
• 语种: 英文

摘要

One new zinc coordination polymer,[Zn（NAA）2（4,4＇-bpy）]n（1,HNAA = 1-naphthaleneacetic acid,4,4＇-bpy = 4,4＇-bipyridine）,has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis（TGA）,and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720（6）,b = 16.7397（9）,c = 17.0371（12） ,β = 104.8080（10）°,V = 2721.9（3）3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ（MoKα） = 0.946 mm-1,F（000） = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I 〉 2σ（I）.1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated.