Crystal Structure of 6,6＇-（3,3＇,5,5＇-Tetra-tert-butylbiphenyl-2,2＇-diyl）bis（oxy）didibenzo-[d,f]-[1,3,2]dioxaphosphepine

• 作者: 冯静 朱丽琴 袁浩 郭浩然
• 来源期刊: 结构化学
• 学科: 其他
• 关键词: diphosphite,crystal structure,hydroformylation,π…π interaction
• 年，卷（期）: 2012,（5）
• 页码范围: 673-676
• 页数: 4页
• 分类号: O
• 语种: 英文

摘要

The title complex,6,6-（3,3,5,5-tetra-tert-butylbiphenyl-2,2-diyl）bis（oxy）di-di-benzo[d,f]-[1,3,2] dioxaphosphepine（C52H56O6P2·C6H14,Mr = 881.99）,was synthesized,and the structure was determined by X-ray single-crystal diffraction.The crystal belongs to the orthor-hombic system,space group Pbca,with a = 11.8400（13）,b = 25.381（3）,c = 34.243（4） ,V = 10290（2）（A°）^3,Z = 8,Dc = 1.139 g/cm^3,μ = 0.131 mm^-1,T = 152（2） K,F（000） = 3768,the final R = 0.0773 and wR = 0.1820 for 9721 observed reflections with I 〉 2σ（I）.The neighboring two molecules form a dimmer by face-to-face π…π interactions.