Synthesis and Crystal Structure of a New Adamantane Amide Derivative

• 作者: CHENG Yong LV Qi-Chun SHENG En-Hong ZHANG Qian ZHOU Ying-Hua
• 来源期刊: 结构化学
• 学科: 化学
• 关键词: 酰胺衍生物 晶体结构 金刚烷 合成 单晶X-射线衍射 NMR谱 元素分析 三斜晶系
• 年，卷（期）: 2012,（4）
• 页码范围: 467-472
• 页数: 6页
• 分类号: O614.121|TQ464.71
• 语种: 英文

摘要

A novel adamantane acyl amide derivative containing two phthalimido pendant groups(C31H31N3O5) has been synthesized,and its structure was characterized by elemental analysis,IR,1 H NMR spectra,and single-crystal X-ray diffraction.The crystal belongs to triclinic,space group P1 with a=7.3158(10),b=13.2405(18),c=14.378(2),α=72.419(2),β=84.496(2),γ=81.799(2)o,V=1312.0(3)3,Z=2,Dc=1.330 g/cm 3,μ=0.09 mm-1,Mr=525.59,F(000)=556,S=1.001,R=0.0523 and wR=0.0707 for 5901 unique reflections with 2363 observed ones(I〉2σ(I)).π-π stacking interactions(offset face-to-face) exist between the two rings of phthalimides from the neighboring molecules in the title crystal structure.The intermolecular dihedral angle between the two rings of neighboring phthalic amides is 6.26° and the distance is 4.008.

作者信息

序号	姓名	单位	发文数	被引次数	H指数	G指数
1	ZHOU Ying-Hua		1	0	0.0	0.0
2	LV Qi-Chun		1	0	0.0	0.0
3	ZHANG Qian		1	0	0.0	0.0
4	CHENG Yong		1	0	0.0	0.0
5	SHENG En-Hong		1	0	0.0	0.0