Syntheses and Crystal Structures of Two One-dimensional Cobalt（II） Compounds with the Flexible Dipyridyl Ligand

• 作者: CUI Zhi-Hua GAO Dong-Zhao SUN Ya-Qiu WANG Si-Si WANG Xiu-Guang XU Yan-Yan ZHANG Guo-Ying
• 来源期刊: 结构化学
• 学科: 化学
• 关键词: 晶体结构 化合物 联吡啶 一维 合成 配体 单晶X-射线衍射 柔性
• 年，卷（期）: 2012,（6）
• 页码范围: 769-776
• 页数: 8页
• 分类号: O614.121|TQ655
• 语种: 英文

摘要

Two one-dimensional cobalt（II） compounds {[Co（Hbpma）（H20）4]2·3SO4·4.5H2O}n 1 and {[Co（Hbpma）（NCS）3（H20）]·2.85H2O}n 2 （bpma = N,N＇-bis（3-pyridylmethyl）amine） have been synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group Pi with a = 15.8780（5）, b = 16.2187（5）, c = 16.4858（5） A, α = 91.0420（10）,β = 94.5190（10）, γ = 101.4360（10）°, V = 4145.7（2） A3, C24H53Co2N6024.5083, Mr = 1031.76, Z = 4, Dc = 1.653 g/cm3, p（MoKa） = 1.046 mm-1, F（000） = 2148, S = 1.017, the final R = 0.0269 and wR = 0.0644 for 13032 observed reflections （I 〉 2a（/））. For complex 2, it belongs to triclinic, space group Pi with a = 9.3761（11）, b = 10.5814（13）, c = 11.2972（14）A, α= 85.472（2）,β = 88.058（2）,γ = 76.203（2）°, V= 1085.0（2） A3, C15Hzl.v0CoN603.85S3, Mr= 502.79, Z = 2, Dc = 1.539 g/cm3, p（MoKa） = 1.112 mm-1, F（000） = 519, S = 1.070, the final R = 0.0358 and wR = 0.0899 for 3466 observed reflections （I 〉 2σ（I））. Two complexes 1 and 2 are both found to be one-dimensional coordination polymers bridged by the protonated bpma ligands, which are assembled into three-dimensional supramolecular structures through the hydrogen bonding interactions and π-π packing interactions.