Synthesis and Crystal Structure of a Two-folded Interpenetrating Three-dimensional Network from Flexible Bisimidazolyl Ligands

• 来源期刊: 结构化学
• 学科: 化学
• 关键词: 晶体结构 三维网络 三维配位聚合物 合成 配体 水热反应 多孔网络 平衡系统
• 年，卷（期）: 2012,（2）
• 页码范围: 235-239
• 页数: 5页
• 分类号: O614.121|TP393
• 语种: 英文

摘要

The hydrothermal reaction of 1,2-bis（imidazol-1′-yl）ethane （Bime） and Ni（NO3）2·6H2O gave rise to a two-folded interpenetrating 3D coordination polymer, [Ni（Bime）3·（NO3）2]n. Singlecrystal X-ray diffraction analyses show that the complex crystallizes in rhombohedral space group R-3. Ni（II） lies on a crystallographic S6 centre and connects six bimes into a 3D porous network. Bime exhibits an anti conformation. NO3- locates as the void filler to balance the charge in the system. The framework is stable through the two-folded interpenetration among the building units.