Synthesis and Crystal Structure of 9-（4-Dimethylaminophenyl）-l,8-dioxo- 9H-dibenzo [c,h ]-2,7,10-trioxanthene

• 作者: JIA Xin-Gang LIU Jian LV Chang-Wei WU Yao-Ping
• 来源期刊: 结构化学
• 学科: 化学
• 关键词: 二甲氨基苯基 反应合成 二氧代 二苯并 晶体结构 X-射线单晶衍射 标题化合物 化学结构
• 年，卷（期）: 2012,（6）
• 页码范围: 843-846
• 页数: 4页
• 分类号: O626.13|TB333
• 语种: 英文

摘要

The title compound 9-（4-dimethylaminophenyl）-1,8-dioxo-9H-dibenzo[c,h]- 2,7,10-trioxanthene （3） was synthesized by the reaction of 4-hydroxycoumarin with 4-dimethyla- minobenzaldehyde, and its chemical structure was determined by X-ray single-crystal diffraction. It crystallizes in triclinic, space group P1 with a = 7.8753（16）, b = 11.029（2）, c = 12.913（3） A, ct = 69.79（3）, β= 89.01（3）, γ = 81.90（3）°, V = 1041.5（4） A3, Z = 2, F（000） = 456, Dc = 1.395 Mg/m3, M,. = 437.43, μ= 0.097 mm-1, 2 = 0.71073 A, the final R = 0.0491 and wR = 0.1314 for 2662 observed reflections with I 〉 2σ（I）.