Enhancement of upconversion luminescence of YAlO3: Er3+ by Gd3+ doping
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摘要:
The upconversion luminescences of YAlO3:Er3+ phosphor co-doping with different Gd3+ concentrations are investigated under the excitation of 980- and 532-nm diode lasers.A near ultraviolet upconversion emission at 410 nm is observed in YAlO3 under 532-nm excitation.Moreover,the inactive Gd3+ ions can improve the upconversion intensity efficiently in a certain range of concentration.Under 980-nm excitation,the visible upconversion emissions at 546 and 646 nm are enhanced by about 10 and 8 times at the Gd3+concentration of 40%,respectively.The upconversion emission at 410 nm under 532-nm excitation is also enhanced by 7 times.The substitution of Gd3+ ions for y3+ sites changes the local symmetry of Er3+,leading to the improvement of upconversion efficiency.