Synthesis, crystal structure, and catalytic properties of 2,2’-bipyridyl-dicyano-palladium(II)

• 作者: Longguan Zhu Xiaoli Tang
• 来源期刊: 无机化学期刊(英文)
• 学科: 化学
• 关键词: SYNTHESIS Thioanisol Pd Complex Oxidation of SULFIDE Hydrogen PEROXIDE DISPROPORTIONATION
• 年，卷（期）: 2013,（4）
• 页码范围: 71-75
• 页数: 5页
• 分类号: O6

摘要

In the solvothermal condition, a Pd(II) complex with a in situ synthesis ligand, [Pd(2,2’-bipy)2(CN)2] (1) was obtained and characterized by elemental analysis, IR, UV, TG, and powder X-ray analysis. The single crystal X-ray analysis showed that the title complex is different from the reported 2,2’-bipyridyl-dicyanopalladium(II) (2) in crystal system and structural parameters. The catalytic investigation for the reactions of the disproportionation of hydrogen peroxide and oxidation of sulfide showed that the complex 1 is an active homogeneous catalyst in the presence of imidazole and 2-sulfobenzoic acid, respectively.